KDP, DKDP crystals
Main features
- Excellent ultraviolet radiation transmission
- The high laser-induced damage threshold
- Custom crystals available upon request
Application examples
- Frequency doublers, triplers, and quadruplers for Nd-doped lasers
- Q-switches for Ti:Sapphire, Alexandrite, Nd-doped lasers
- Description
- Properties
- Standard specifications
Potassium dihydrogen phosphate (KH2PO4, KDP) and potassium dideuterium phosphate (KD2PO4, DKDP) crystals are one of the oldest used nonlinear materials. DKDP and KDP are known as analogs, though their properties differ due to DKDP deuteration. They both exhibit excellent ultraviolet transmission and high damage threshold. The nonlinearity of these crystals is relatively low, these crystals can be grown in large size. They found their application as nonlinear frequency doublers, triplers, and quandruplers of Nd-doped lasers and as Q-switch devices for Ti:Sapphire, Alexandrite, Nd-doped lasers. The main drawback is that these crystals are highly hygroscopic, therefore sealed housing and dry operating conditions have to be ensured.
Physical and optical properties | ||
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Chemical formula | KH2PO4 (KDP) | KD2PO4 (DKDP) |
Crystal structure | Tetragonal, 42m | Tetragonal, 42m |
Lattice parameters | a= 7,448 Å, c= 6,977 Å | a= 7,4697 Å, c= 6,966 Å |
Optical symmetry | Negative uniaxial (no > ne) | Negative uniaxial (no > ne) |
Density | 2,332 g/cm3 | 2,355 g/cm3 |
Mohs hardness | 2,5 | 2,5 |
Transparency range | 180 nm - 1,5 μm | 200 nm - 2 μm |
Refractive indices | no = 1,4938, ne = 1,4599 @1,06 µm | no = 1,4931; ne = 1,4582 @1,06 µm |
KDP Sellmeier equations @T = 293 k (λ in µm) | no2 = 2,259276 + 13,00522 λ2/(λ2 - 400) + 0,01008956/(λ2 - (77,26408)-1); ne2 = 2,132668 + 3,2279924 λ2/(λ2 - 400) + 0,008637494/(λ2 - (81,42631)2) |
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DKDP Sellmeier equations @T = 293 K (λ in µm) | no2 = 2,240921 + 2,246956 λ2/(λ2 - (11,26591)2) + 0,009676/(λ2 - (0,124981)2); ne2 = 2,126019 + 0,784404 λ2/(λ2 - (11,10871)2) + 0,008578/(λ2 - (0,109505)2) |
KDP and DKDP crystals | |
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Orientation accuracy | <30 arcmin |
Clear aperture | >90% |
Face dimensions tolerance | +0,0/-0,1 mm |
Length tolerance | ±0,1 mm |
Parallelism error | <20 arcsec |
Perpendicularity error | <5 arcmin |
Protective chamfers | <0,1 mm at 45° |
Surface quality | 20-10 S-D |
Wavefront flatness | <λ/4@632,8 nm |
Coatings | AR coatings on both sides |
Laser-induced damage threshold | >10 J/cm2@1064 nm, 10 ns for KDP crystals >5 J/cm2@1064 nm, 10 ns for DKDP |
Mount | Unmounted |