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Senior sales engineer
Arminas Butkus +370 5 219 4884
Er, Yb:phosphate glass
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Er, Yb:phosphate glass

Main features

 

  • Long lifetime of the 4I13/2 erbium energy level
  • High Yb to Er energy transfer efficiency
  • High absorption and emission cross-sections
  • Wide absorption and emission bandwidths
  • Custom crystals available upon request

 

Application examples

 

  • Passively Q-switched lasers for laser rangefinders, LIDAR, and LIBS systems
Request custom View stock
  • Description
  • Properties
  • Absorption and emission curves
  • Standard specifications

Er3+, Yb3+ co-doped phosphate glass (Er, Yb:phosphate glass) is a well-known and commonly used active medium for lasers emitting in the “eye-safe” spectral range of 1,5-1,6 µm. Phosphate glass combines a long lifetime (~8 ms) of 4I13/2 Er3+ upper laser level with a low (2–3 ms) lifetime of  4I11/2Er3+ level that is in resonance with Yb3+ 2F5/2 excited state. Fast non-radiative multi-phonon relaxation from 4I11/2 to 4I13/2 level greatly decreases the back-energy transfer and up-conversion losses due to the interaction between Yb3+ and Er3+ ions, excited at the 2F5/2 and the 4I11/2 levels, respectively.

Spectroscopic and thermo-mechanical properties
Absorption peak wavelength 970 nm
Absorption cross-section at a peak wavelength 1,7×10-20 cm2
Absorption bandwidth at a peak wavelength 20 nm
Laser wavelength 1534 nm
Lifetime of 4I13/2 erbium energy level 7,9 ms
Emission cross-section @1534 nm 8 × 10-21 cm2
Yb to Er energy transfer efficiency >90 %
Refractive index @1534 nm 1,52
Crystal structure -
Density 2,93 g/cm3
Mohs hardness 6-7
Thermal conductivity 0,85 Wm-1K-1
dn/dT -2,1 × 10-6 K-1
Thermal expansion coefficient 12,4 × 10-6 K-1
Typical doping level 0,3-1,3 × 1020 cm-3 [Er]
1,7-4 × 1021 cm-3 [Yb]

Er, Yb:phosphate glass crystals
Clear aperture >90%
Face dimensions tolerance +0,0/-0,1 mm
Length tolerance ±0,1 mm
Parallelism error <10 arcsec
Perpendicularity error <10 arcmin
Protective chamfers <0,1 mm at 45˚
Surface quality 10-5 S-D
Surface flatness <λ/10@632,8 nm
Coatings AR(R<0,5%)@940 nm + AR(R<0,2%)@1535 nm on both faces
Laser-induced damage threshold >10 J/cm2@1535 nm, 10 ns
Mount Unmounted
Order your item
Face dimensions Length End faces Doping Coatings SKU PRICE QUANTITY
3x3 mm
10 mm
Right angle cut
Yb 20% Er 0,5%
AR/AR@940 nm + 1535 nm
7821
435 €
3x3 mm
10 mm
Brewster cut
Yb 20% Er 0,5%
uncoated
7822
370 €
3x3 mm
5 mm
Right angle cut
Yb 20% Er 1%
AR/AR@940 nm + 1535 nm
7823
435 €
3x3 mm
5 mm
Brewster cut
Yb 20% Er 1%
uncoated
7824
370 €